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In standard it was the core to the aptly named Puresteel Paladin deck, using its main ability to draw into more action and later on the metalcraft ability to cheat out on some equip costs, but it has also seen play in Cheerios, a deck based around 0 mana artifacts and Paradoxical Outcome to eventually cast Grapeshot, and most recently in Hammer Time, which focuses on Colossus Hammer, where Puresteel Paladin once again comes in to both help circumvent equip costs

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However, if you trade Ashiok for Hero's Downfall right away, then you've given up the opportunity to trade a Thoughtseize for the Hero's Downfall should you draw one